BASIC CHROMIC SULFATE

PRODUCT IDENTIFICATION
CAS NO. 12336-95-7 (hydroxide sulfate)

BASIC CHROMIC SULFATE
EINECS NO. 235-595-8, 233-253-2
FORMULA Cr2(SO4)3
MOL WT. 392.16

H.S. CODE

  
TOXICITY

 
SYNONYMS Chromium hydroxide sulfate;

Chromium sulfate (2:3); chromium[III] sulfate; dichromium sulfate; dichromium tris(sulfate); dichromium trisulfate; sulfuric acid, chromium (III) salt (3:2); C.I.77305
SMILES  

CLASSIFICATION

 

PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE green powder
MELTING POINT  
BOILING POINT  
SPECIFIC GRAVITY 1.25
SOLUBILITY IN WATER soluble
pH  
VAPOR DENSITY  

REFRACTIVE INDEX

 

NFPA RATINGS

  

AUTOIGNITION

  
FLASH POINT  
STABILITY Stable under ordinary conditions.

GENERAL DESCRIPTION  & APPLICATIONS
Chromium (symbol Cr and atomic number 24) occurs in the oxidation states 0, +2, +3, and +6 states. Element (0) and divalent chromium, however, are unstable. Chromium (0) immediately produce a thin oxide layer. Divalent chromium is easily oxidized to the trivalent form in air. The trivalent and hexavalent oxidation states are important in industry, which exit in their divalent anions called chromate and dichromate respectively and an chromic anhydride form called chromium trioxide (CrO3) and chromic oxide (Cr2O3). In industrial, chromium trioxide is called chromic acid. The principal uses of chromium are in the metallurgical processing of ferrochromium and other metallurgical products to impart corrosion resistance, chiefly stainless steel. There are applications in chrome plating, anodizing aluminium, and refractory processing of chrome brick. When combined with oxygen together other metallic elements such as lead and potassium, it forms various inorganic pigments. Chromium is used in chemical processing to produce chromic acid and chromates. Chromates are strong oxidants which will produce many organic and inorganic materials and used in the purification of chemicals. Chromates are used as rust and corrosion inhibitors in diesel engines. Dichromate is converted to chromic sulfate for tanning of leather. The reaction of chromium with collagen raises the hydrothermal stability of the leather and renders it resistant to bacterial attack. The reaction with collagen is useful reaction in screen printing application and in photography as a sensitizer for gelatin coatings. This Chromates and dichromates are used as pigments in paints and in dyeing. Chrome colors include black, red, orange, green, and yellow. Chromate salts contain the chromate ion, CrO4-2, and have an intense yellow color. Dichromate salts contain the dichromate ion, Cr2O7-2, and have an intense orange color. Chromates are used as mordant in dyeing cloth.

Chromic acid ( chromium trioxide, CrO3) is an odorless red deliquescent solid. Chromium trioxide is produced commercially by the reaction of sodium dichromate with concentrated sulfuric acid. It has been used mainly for chromium plating particularly in the production of automobiles and as a colorant in ceramics. Uses in other metal-finishing operations include aluminium anodizing, particularly on military aircraft; chemical conversion coatings, which provide both decoration and corrosion protection; and the production of phosphate films on galvanized iron or steel. It is a powerful oxidant and are utilized by controlled oxidations in organic synthesis. This compound is sensitive to moisture.

Another significant oxygen compound, chromic oxide is prepared by calcining sodium dichromate with boric acid or by reducing sodium dichromate with carbon. Anhydrous chromic oxide is produced commercially from chromic hydroxide, dry ammonium dichromate, or sodium dichromate by heating  with sulfur. Chromic oxide is a dark green, amorphous powder, forming hexagonal crystals on heating that are insoluble in water or acids. Most chromic oxide is used as a pigment. Anhydrous chromic oxide is known as the most stable green pigment used when heat, light and chemical resistance is required for glass, ceramics, and polymers. Its hydrate form is called Guignet's green and used as a green pigment, particularly for automotive finishes.

Chromic compounds are also used in metallurgy in the manufacture of chromium metal and aluminium-chromium master alloys, in refractory brick, and as a chemical intermediate. They have good resistance to alkali and find application as colorant for latex paints. They are used in asphalt roofing and in camouflage paints. They are used as catalyst in the preparation of methanol, butadiene and high-density polyethylene. When used as a mild abrasive for polishing jewellery and fine metal parts, it is known as ¡®green rouge¡¯

Chromic compounds are used extensively as pigments. Chromic acid finds applications in:

  • wood Preservative
  • Metal Plating
  • Magnetic Tape
  • Catalyst
  • Copper stripping
  • Aluminum anodizing
  • Corrosion inhibitor
  • Photography
  • Purifying oil and acetylene
  • Oxidizer in organic synthesis

Basic chromic sulfates are the mixtures of various form of chromic sulfates including containing chromium hydroxide sulfate form chiefly, Cr(OH)SO4. It is prepared by the reduction of sodium dichromate solution in the presence of sulfuric acid or sulfur dioxide. Basic chromic sulfate is the principal ingredient for leather tanning. Chromic sulfate is used in preparing chrome plating and chromium alloys. It is used as a green pigment for paints, varnishes, inks, and ceramic glazes. It is used as a mordant for textile dyeing.

SALES SPECIFICATION

APPEARANCE

Green crystal powder

Cr2O3

24 - 26%

BASICITY

32 - 34%
Fe

0.1% max

WATER INSOLUBLES

0.1% max
TRANSPORTATION
PACKING 25kgs in Bag, 20mts in Container
HAZARD CLASS  
UN NO.  
OTHER INFORMATION
CAS RN of Chromium Sulfates
12336-95-7 (chromium hydroxide sulfate)
39380-78-4 (chromium hydroxide sulfate)
72993-54-5 (chromium hydroxide sulfate)
15244-38-9 (chromium sulfate hydrate)
39378-25-1 (unspecified chromium sulfate salt)
10101-53-8 (sulfuric acid, chromium(III) salt (3:2), 12-hydrate)
17854-98-7(chromium(III) sodium sulfate dodecahydrate)
10031-37-5 (chromium(III) [3:2] salt pentadecahydrate)
13825-86-0 (chromium(II)[1:1] salt)
14489-25-9 (unspecified chromium sulfate salt)
15005-90-0 (chromium(III) [3:2] salt hexahydrate)
64093-79-4 (neochromium; monobasic chromium sulfate)